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dc.contributor.authorNeo, Kian Eang
dc.contributor.authorHuynh, Han Vinh
dc.contributor.authorKoh, Lip Lin
dc.contributor.authorHenderson, William
dc.contributor.authorHor, T.S. Andy
dc.date.accessioned2009-11-27T00:17:02Z
dc.date.available2009-11-27T00:17:02Z
dc.date.issued2008
dc.identifier.citationNeo, K. E., Huynh, H. V., Koh, L. L., Henderson, W., Hor, T. S. A. (2008). Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II). Journal of Organometallic Chemistry, 693(8/9), 1628-1635.en
dc.identifier.urihttps://hdl.handle.net/10289/3429
dc.description.abstractPincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = −CH(CH₂CH₂PPh₂)₂) reacts with AgNO₃ to give [Pd(NO₃)(PCP)] (2). Similar reaction with AgBF₄ gives the aqua complex [Pd(OH₂)(PCP)][BF₄] (3) and the dinuclear complex [{Pd(PCP)}₂(μ-Cl)][BF₄] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki–Miyaura coupling between aryl bromides and phenyl boronic acid.en
dc.language.isoen
dc.publisherElsevieren_NZ
dc.subjectpinceren
dc.subjectpalladiumen
dc.subjectphosphineen
dc.subjectsuzuki–miyaura couplingen
dc.titleIsolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)en
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.jorganchem.2007.11.031en
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page1628en_NZ
pubs.elements-id32934
pubs.end-page1635en_NZ
pubs.issue8-9en_NZ
pubs.volume693en_NZ


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