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dc.contributor.authorDeadman, Benjamin Jade
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorPetchell, Laura Eleanor
dc.contributor.authorRose, Sarah L.
dc.contributor.authorHor, T.S. Andy
dc.date.accessioned2009-11-30T02:04:44Z
dc.date.available2009-11-30T02:04:44Z
dc.date.issued2009
dc.identifier.citationDeadman, B. J., Henderson, W., Nicholson, B. K., Petchell, L. E., Rose, S. L., & Hor, T. S. A. (2009). The arylation of [Pt₂(μ-S)₂(PPh₃)₄]. Inorganica Chimica Acta.en
dc.identifier.urihttps://hdl.handle.net/10289/3444
dc.description.abstractRoutes to the synthesis of the mixed sulfide-phenylthiolate complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ have been explored; reaction of [Pt₂(μ-S)₂(PPh₃)₄] with excess Ph₂IBr proceeds readily to selectively produce this complex, which was structurally characterised as its PF₆⁻ salt. Reactions of [Pt₂(μ-S)₂(PPh₃)₄] with other potent arylating reagents (1-chloro-2,4-dinitrobenzene and 1,5-difluoro-2,4-dinitrobenzene) also produce the corresponding nitroarylthiolate complexes [Pt₂(μ-S){μ -SC₆H₂(NO₂)₂X}(PPh₃)₄]⁺ (X = H, F). The complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ reacts with Me₂SO₄ to produce the mixed alkyl/aryl bis-thiolate complex [Pt₂(μ-SMe)(μ -SPh)(PPh₃)₄]²⁺, but corresponding reactions with the nitroarylthiolate complexes are plagued by elimination of the nitroaryl group and formation of [Pt₂(μ-SMe)₂(PPh₃)₄]²⁺. [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ also reacts with Ph₃PAuCl to give [Pt₂(μ-SAuPPh₃)(μ -SPh)(PPh₃)₄]²⁺.en
dc.language.isoen
dc.publisherElsevieren_NZ
dc.subjectplatinum complexesen
dc.subjectthiolate complexesen
dc.subjectsulfide complexesen
dc.subjectcrystal structureen
dc.subjectelectrospray mass spectrometryen
dc.titleThe arylation of [Pt₂(μ-S)₂(PPh₃)₄]en
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.ica.2009.11.012en
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page637en_NZ
pubs.elements-id34550
pubs.end-page644en_NZ
pubs.issue4en_NZ
pubs.volume363en_NZ


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