dc.contributor.author | Bruce, Michael I. | |
dc.contributor.author | Low, Paul J. | |
dc.contributor.author | Nicholson, Brian K. | |
dc.contributor.author | Skelton, Brian W. | |
dc.contributor.author | Zaitseva, Natasha N. | |
dc.contributor.author | Zhao, Xiao-li | |
dc.date.accessioned | 2010-06-29T00:03:25Z | |
dc.date.available | 2010-06-29T00:03:25Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Bruce, M.I., Low, P.J., Nicholson, B.K., Skelton, B.W., Zaitseva, N.N. & Zhao, X. (2010). Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂](BF₄)₂ (M = Ag, Cu). Journal of Organometallic Chemistry, 695(10-11), 1569-1575. | en_NZ |
dc.identifier.uri | https://hdl.handle.net/10289/4058 | |
dc.description.abstract | Reactions between [M2(dppm)2(NCMe)2]X2 [M = Ag, X = ClO₄; M = Cu, X = BF₄] and Ru(C CC CM)(dppe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO₃ or CuCl(PPh₃), respectively] afford the cationic mixed-metal cluster diynyl complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂]X₂, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M₂(μ-dppm)₂(NCMe)₂](BF₄)₂ and Ru(C CC CM′)(dppe)Cp* (M,M′ = Cu, Ag) afforded a mixture of Ag6−nCun clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive disproportionation occurs in solution. | en_NZ |
dc.language.iso | en | |
dc.publisher | Elsevier | en_NZ |
dc.subject | cluster | en_NZ |
dc.subject | diyne | en_NZ |
dc.subject | copper | en_NZ |
dc.subject | silver | en_NZ |
dc.subject | ruthenium | en_NZ |
dc.subject | structure | en_NZ |
dc.title | Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂](BF₄)₂ (M = Ag, Cu) | en_NZ |
dc.type | Journal Article | en_NZ |
dc.identifier.doi | 10.1016/j.jorganchem.2010.03.016 | en_NZ |
dc.relation.isPartOf | Journal of Organometallic Chemistry | en_NZ |
pubs.begin-page | 1569 | en_NZ |
pubs.elements-id | 35001 | |
pubs.end-page | 1575 | en_NZ |
pubs.volume | 695 | en_NZ |