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dc.contributor.authorBruce, Michael I.
dc.contributor.authorLow, Paul J.
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorZaitseva, Natasha N.
dc.contributor.authorZhao, Xiao-li
dc.date.accessioned2010-06-29T00:03:25Z
dc.date.available2010-06-29T00:03:25Z
dc.date.issued2010
dc.identifier.citationBruce, M.I., Low, P.J., Nicholson, B.K., Skelton, B.W., Zaitseva, N.N. & Zhao, X. (2010). Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂](BF₄)₂ (M = Ag, Cu). Journal of Organometallic Chemistry, 695(10-11), 1569-1575.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/4058
dc.description.abstractReactions between [M2(dppm)2(NCMe)2]X2 [M = Ag, X = ClO₄; M = Cu, X = BF₄] and Ru(C CC CM)(dppe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO₃ or CuCl(PPh₃), respectively] afford the cationic mixed-metal cluster diynyl complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂]X₂, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M₂(μ-dppm)₂(NCMe)₂](BF₄)₂ and Ru(C CC CM′)(dppe)Cp* (M,M′ = Cu, Ag) afforded a mixture of Ag6−nCun clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive disproportionation occurs in solution.en_NZ
dc.language.isoen
dc.publisherElsevieren_NZ
dc.subjectclusteren_NZ
dc.subjectdiyneen_NZ
dc.subjectcopperen_NZ
dc.subjectsilveren_NZ
dc.subjectrutheniumen_NZ
dc.subjectstructureen_NZ
dc.titlePreparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M₆{μ₃-C CC C[Ru(dppe)Cp*]}₄(μ-dppm)₂](BF₄)₂ (M = Ag, Cu)en_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.jorganchem.2010.03.016en_NZ
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page1569en_NZ
pubs.elements-id35001
pubs.end-page1575en_NZ
pubs.volume695en_NZ


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