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      Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]

      Ujam, Oguejiofo Theophilus; Devoy, Sarah M.; Henderson, William; Nicholson, Brian K.; Hor, T.S. Andy
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      final bl Ujams monoalkylation manuscript.pdf
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      DOI
       10.1016/j.ica.2010.07.011
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      Ujam, O.T., Devoy, S.M., Henderson, W., Nicholson, B.K. & Hor, T.S.A. (2010). Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]. Inorganica Chimica Acta, Available online 14 July 2010.
      Permanent Research Commons link: https://hdl.handle.net/10289/4218
      Abstract
      Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt₂(μ-S)₂(PPh₃)₄]with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt₂(μ-S)(μ-SR)(PPh₃)₄]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups.
      Date
      2010
      Type
      Journal Article
      Publisher
      Elsevier
      Rights
      This is an author’s accepted version of an article published in the journal: Inorganica Chimica Acta. © 2010 Elsevier.
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      • Science and Engineering Papers [3019]
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