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dc.contributor.authorUjam, Oguejiofo Theophilus
dc.contributor.authorDevoy, Sarah M.
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorHor, T.S. Andy
dc.date.accessioned2010-07-30T03:23:28Z
dc.date.available2010-07-30T03:23:28Z
dc.date.issued2010
dc.identifier.citationUjam, O.T., Devoy, S.M., Henderson, W., Nicholson, B.K. & Hor, T.S.A. (2010). Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]. Inorganica Chimica Acta, Available online 14 July 2010.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/4218
dc.description.abstractAlkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt₂(μ-S)₂(PPh₃)₄]with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt₂(μ-S)(μ-SR)(PPh₃)₄]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevieren_NZ
dc.rightsThis is an author’s accepted version of an article published in the journal: Inorganica Chimica Acta. © 2010 Elsevier.en_NZ
dc.subjectplatinum complexesen_NZ
dc.subjectsulfido complexesen_NZ
dc.subjectthiolate complexesen_NZ
dc.subjectcrystal structureen_NZ
dc.subjectalkylation reactions healthen_NZ
dc.titleDinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]en_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.ica.2010.07.011en_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page3558en_NZ
pubs.elements-id35192
pubs.end-page3568en_NZ
pubs.issue13en_NZ
pubs.volume363en_NZ


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