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dc.contributor.authorWhite, Bradley C.
dc.contributor.authorHarrison, Dylan
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorHor, T.S. Andy
dc.date.accessioned2010-08-17T00:06:26Z
dc.date.available2010-08-17T00:06:26Z
dc.date.issued2010-08
dc.identifier.citationWhite, B.C., Harrison, D., Henderson, W., Nicholson, B.K. & Hor, T.S.A. (2010). Synthesis and characterisation of adducts of [Pt₂(μ-S) ₂(PPh₃)₄] with organo-palladium and platinum-hydride substrates. Inorganica Chimica Acta, 363(11), 2387-2393.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/4357
dc.description.abstractThe reactions of [Pt₂(μ-S) ₂(PPh₃)₄] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η³-allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt₂PdS₂} cores. [Pt₂(μ-S) ₂(PPh₃)₄] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)₂] giving the adduct [Pt₂(μ-S) ₂ (PPh₃)₄PtH(PPh₃)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S) ₂ (PPh₃)₄PdPh(PPh₃)]PF₆ and [Pt₂ (μ-S) ₂ (PPh₃)₄PtH(PPh₃)]PF₆ are reported, and show the expected bis μ₃-sulfido aggregates with three square-planar metal centres.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevieren_NZ
dc.rightsThis is an author’s accepted manuscript version of an article published in the journal: Inorganica Chemica Acta. Copyright © 2010 Elsevier B.V.
dc.subjectplatinum complexesen_NZ
dc.subjectpalladium complexesen_NZ
dc.subjecttrinuclear complexesen_NZ
dc.subjectsulfido ligandsen_NZ
dc.subjectelectrospray mass spectrometryen_NZ
dc.subjectcrystal structureen_NZ
dc.titleSynthesis and characterisation of adducts of [Pt₂(μ-S) ₂(PPh₃)₄] with organo-palladium and platinum-hydride substratesen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.ica.2010.03.068en_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page2387en_NZ
pubs.elements-id35229
pubs.end-page2393en_NZ
pubs.issue11en_NZ
pubs.volume363en_NZ


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