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dc.contributor.authorDecker, Corry
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2010-08-19T23:59:53Z
dc.date.available2010-08-19T23:59:53Z
dc.date.issued2010-09
dc.identifier.citationDecker, C., Henderson, W. & Nicholson, B. K. (2010). Platinum(II), palladium(II), nickel(II), and gold(I) complexes of the “electrospray-friendly” thiolate ligands 4-SC₅H₄N- and 4-SC₆H₄OMe-. Journal of Coordination Chemistry, 63(17), 2965-2975.en_NZ
dc.identifier.issn1029-0389
dc.identifier.urihttps://hdl.handle.net/10289/4377
dc.description.abstractThe series of platinum(II), palladium(II), and nickel(II) complexes [ML₂(dppe)] [M = Ni, Pd, Pt; L = 4-SC₅H₄N or 4-SC₆H₄OMe; dppe = Ph₂PCH₂CH₂PPh₂] containing pyridine-4-thiolate or 4-methoxybenzenethiolate ligands, together with the corresponding gold(I) complexes [AuL(PPh3)], were prepared and their electrospray ionization mass spectrometric behavior compared with that of the thiophenolate complexes [M(SPh)₂(dppe)] (M = Ni, Pd, Pt) and [Au(SPh)(PPh₃)]. While the pyridine-4-thiolate complexes yielded protonated ions of the type [M + H]+ and [M + 2H]²+ ions in the Ni, Pd, and Pt complexes, an [M + H]+ ion was only observed for the platinum derivative of 4-methoxybenzenethiolate. Other ions, which dominated the spectra of the thiophenolate complexes, were formed by thiolate loss and aggregate formation. The X-ray crystal structure of [Pt(SC₆H₄OMe-4)₂(dppe)] is also reported.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherTaylor & Francisen_NZ
dc.rightsThis is an electronic version of an article published in the Journal of Coordination Chemistry, which is available online at: www.tandfonline.com
dc.subjectthiolate ligandsen_NZ
dc.subjectelectrospray ionization mass spectrometryen_NZ
dc.subjectplatinum complexesen_NZ
dc.subjectpalladium complexesen_NZ
dc.subjectnickel complexesen_NZ
dc.subjectgold complexesen_NZ
dc.titlePlatinum(II), palladium(II), nickel(II), and gold(I) complexes of the “electrospray-friendly” thiolate ligands 4-SC₅H₄N- and 4-SC₆H₄OMe-en_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1080/00958972.2010.507270en_NZ
dc.relation.isPartOfJournal of Coordination Chemistryen_NZ
pubs.begin-page2965en_NZ
pubs.elements-id35263
pubs.end-page2975en_NZ
pubs.issue17en_NZ
pubs.volume63en_NZ
uow.identifier.article-noPII 925290295en_NZ


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