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      Transition metal carbonyl derivatives of the germanes: XIV. Studies of mixed cobalt carbonyl/manganese carbonyl substituted germanes including [(CO)₅MnGeCo₃(CO)₉], μ₃-(pentacarbonylmanganesegermylidyne)cyclotris(tricarbonylcobalt)(3Co---Co)

      Christie, Judy A.; Duffy, D. Neil; Mackay, Kenneth M.; Nicholson, Brian K.
      DOI
       10.1016/S0022-328X(00)87432-X
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      Christie, J.A., Duffy, D.N., Mackay, K.M. & Nicholson, B.K. (1982). Transition metal carbonyl derivatives of the germanes: XIV. Studies of mixed cobalt carbonyl/manganese carbonyl substituted germanes including [(CO)₅MnGeCo₃(CO)₉], μ₃-(pentacarbonylmanganesegermylidyne)cyclotris(tricarbonylcobalt)(3Co---Co). Journal of Organometallic Chemistry, 226(2), 165-169.
      Permanent Research Commons link: https://hdl.handle.net/10289/4733
      Abstract
      [Mn(CO)₅GeH₃] reacts smoothly with Co₂(CO)₈ to form the [(CO)₅MnGeCo₃(CO)₉], which is also produced by the reaction of Mn(CO)₅⁻ with [(CO)₄CoGeCo₃(CO)₉]. [Mn(CO)₅GeMeH₂] similarly reacts with Co₂(CO)₈ to give [{Mn(CO)₅} {Co₂(CO)₇}GeMe]. The products were characterised spectroscopically and the ESR spectrum of the radical ion of the title compound is presented.
      Date
      1982
      Type
      Journal Article
      Publisher
      Elsevier
      Collections
      • Science and Engineering Papers [3069]
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