| dc.contributor.author | Ujam, Oguejiofo Theophilus | |
| dc.contributor.author | Devoy, Sarah M. | |
| dc.contributor.author | Henderson, William | |
| dc.contributor.author | Wilkins, Alistair L. | |
| dc.contributor.author | Nicholson, Brian K. | |
| dc.date.accessioned | 2011-09-07T04:49:22Z | |
| dc.date.available | 2011-09-07T04:49:22Z | |
| dc.date.issued | 2011 | |
| dc.identifier.citation | Ujam, O.T., Devoy, S.M., Henderson, W., Wilkins, A.L. & Nicholson, B.K. (2011). E/Z isomerism in monoalkylated derivatives of [Pt₂(μ-S)₂(PPh₃)₄] containing 2,4-dinitrophenylhydrazone substituents. Journal of Coordination Chemistry, 64(16), 2782-2790. | en_NZ |
| dc.identifier.uri | https://hdl.handle.net/10289/5707 | |
| dc.description.abstract | Alkylation of [Pt₂(m-S)₂(PPh₃)₄] with 2,4-dinitrophenylhydrazone-functionalized alkylating agents XC6H4C{¼NNHC₆H₃(NO₂)₂}CH2Br (X¼H, Ph) gives monoalkylated cations [Pt₂(m-S){m-SCH₂C{¼NNHC₆H₃(NO₂)₂}C₆H₄X}(PPh₃)₄]⁺. An X-ray diffraction study on [Pt₂(m-S){m-SCH₂C{¼NNHC₆H₃(NO₂)₂}Ph}(PPh₃)₄]BPh₄ shows the crystal to be the Z isomer, with the phenyl ring and NHC₆H₃(NO₂)₂ groups mutually trans. ¹H- and ³¹P{¹H} NMR spectroscopic methods indicate a mixture of Z (major) and E (minor) isomers in solution, which slowly convert mainly to the E isomer. Reaction of [Pt₂(m-S)₂ (PPh₃)₄] with the dinitrophenylhydrazone of chloroacetone [ClCH₂C{¼NNH(C₆H₃(NO₂)₂}Me] and NaBPh₄ gives [Pt₂ (m-S){m-SCH₂C{¼NNHC₆H₃(NO₂)₂}Me}(PPh₃)₄]BPh₄, which exists as a single (E) isomer. | en_NZ |
| dc.language.iso | en | |
| dc.relation.uri | http://www.tandfonline.com/doi/abs/10.1080/00958972.2011.606573 | en_NZ |
| dc.subject | Platinum complexes | en_NZ |
| dc.subject | alkylation reactions | en_NZ |
| dc.subject | electrospray ionization mass spectrometry | en_NZ |
| dc.subject | X-ray crystal structure | en_NZ |
| dc.subject | Dinitrophenylhydrazones | en_NZ |
| dc.title | E/Z isomerism in monoalkylated derivatives of [Pt₂(μ-S)₂(PPh₃)₄] containing 2,4-dinitrophenylhydrazone substituents | en_NZ |
| dc.type | Journal Article | en_NZ |
| dc.identifier.doi | 10.1080/00958972.2011.606573 | en_NZ |
