| dc.contributor.author | Nicholson, Brian K. | |
| dc.contributor.author | Clark, Christopher J. | |
| dc.contributor.author | Wright, Cody Elvin | |
| dc.contributor.author | Telfers, Shane G. | |
| dc.contributor.author | Groutso, Tania | |
| dc.date.accessioned | 2012-01-24T03:22:45Z | |
| dc.date.available | 2012-01-24T03:22:45Z | |
| dc.date.issued | 2011 | |
| dc.identifier.citation | Nicholson, B.K., Clark, C.J., Wright, C.E., Telfers, S.G. & Groutso, T. (2011). New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]. Organometallics, 30(24), 6612-6616. | en_NZ |
| dc.identifier.uri | https://hdl.handle.net/10289/5978 | |
| dc.description.abstract | The lithium salt of p-tolylstibonic acid contains the anion [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻, in which the Li⁺ is fully enclosed within an {Sb₁₂O₂₈} cage with γ Keggin ion geometry; the idealized overall formula is Li₅[LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]Br•18H₂O. In contrast, Ba²⁺ induces the formation of the unprecedented {Sb₁₄O₃₄} bowl-shaped polyoxostibonate [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]•4H₂O. Compounds were characterized by single-crystal X-ray crystallography and by ESI-MS. | en_NZ |
| dc.language.iso | en | |
| dc.publisher | American Chemistry Society | en_NZ |
| dc.relation.uri | http://pubs.acs.org/doi/abs/10.1021/om200739a | en_NZ |
| dc.subject | chemistry | en_NZ |
| dc.title | New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄] | en_NZ |
| dc.type | Journal Article | en_NZ |
| dc.identifier.doi | 10.1021/om200739a | en_NZ |
| dc.relation.isPartOf | Organometallics | en_NZ |
| pubs.begin-page | 6612 | en_NZ |
| pubs.elements-id | 36823 | |
| pubs.end-page | 6616 | en_NZ |
| pubs.issue | 24 | en_NZ |
| pubs.volume | 30 | en_NZ |
