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dc.contributor.authorArmitt, David J.
dc.contributor.authorBruce, Michael I.
dc.contributor.authorMorris, Jonathan C.
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorParker, Christian R.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorZaitseva, Natasha N.
dc.date.accessioned2012-01-24T03:44:02Z
dc.date.available2012-01-24T03:44:02Z
dc.date.issued2011
dc.identifier.citationNicholson, B.K., Clark, C.J., Wright, C.E., Telfers, S.G. & Groutso, T. (2011). New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]. Organometallics, 30(24), 6612-6616.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/5979
dc.description.abstractThe bis(metallaethynyl) ketone {(Ph₃P)AuC≡C}₂CO (1), obtained from (Me₃SiC≡C)₂CO, AuCl(PPh₃), and NaOMe, forms an Au•••Au-bonded dimer in the solid state (Au•••Au = 2.9825(3) Å). The ES-MS contains ions [2M + X]⁺ (X = Na, K, Au), but the lack of the ion [2M]⁺ and NMR evidence suggest that the dimeric structure is not preserved in solution. Compound 1 reacts with RuCl(dppe)Cp to afford the unusual dimetal-substituted pyrylium complex [1,3-{Ru(dppe)Cp}₂{c-COC(OMe)CHCCH}]PF₆ (2). The molecular structure of 2 is also reported, together with a proposed route for its formation.en_NZ
dc.language.isoen
dc.publisherAmerican Chemistry Societyen_NZ
dc.relation.urihttp://pubs.acs.org/doi/abs/10.1021/om200659ten_NZ
dc.subjectchemistryen_NZ
dc.titleBis(metallaethynyl) Ketones: Synthesis and Structure of {(Ph₃P)AuC≡C}₂CO and Attempted Transmetalation: Formation and Structure of [1,3-{Ru(dppe)Cp}₂{c-COC(OMe)CHCCH}]PF₆en_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1021/om200659ten_NZ
dc.relation.isPartOfOrganometallicsen_NZ
pubs.begin-page5452en_NZ
pubs.elements-id36821
pubs.end-page5456en_NZ
pubs.issue20en_NZ
pubs.volume30en_NZ


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