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      Cyclometalated gold(III) iminophosphoranes which incorporate carbohydrate groups

      Jarman, Bevan P.; Nicholson, Brian K.
      DOI
       10.1016/j.jorganchem.2011.11.009
      Link
       www.sciencedirect.com
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      Citation
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      Jarman, B.P. & Nicholson, B.K. (2012). Cyclometalated gold(III) iminophosphoranes which incorporatecarbohydrategroups. Journal of Organometallic Chemistry, 702, 1-9.
      Permanent Research Commons link: https://hdl.handle.net/10289/6352
      Abstract
      Iminophosphoranes with organic groups derived from d-glucose, d-galactose and l-arabinose have been used to prepare gold(III) dichloride complexes via mercurated intermediates, since direct cyclometallation was unsuccessful. Structures and full spectroscopic data are reported. Replacement of one or more of the chloride ligands by PPh3, or by thiosalicylate gave new derivatives. Biological screening showed no enhanced activity relative to other alkyl or aryl analogues.
      Date
      2012
      Type
      Journal Article
      Publisher
      Elsevier
      Collections
      • Science and Engineering Papers [3122]
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