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      Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl

      Dai, Yuan; Nicholson, Brian K.
      DOI
       10.1071/CH11395
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      Dai, Y., & Nicholson, B. K. (2012). Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl. Australian Journal of Chemistry, 65(7), 730.
      Permanent Research Commons link: https://hdl.handle.net/10289/6819
      Abstract
      The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.
      Date
      2012
      Type
      Journal Article
      Publisher
      CSIRO Publishing
      Collections
      • Science and Engineering Papers [3121]
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