Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl
Dai, Y., & Nicholson, B. K. (2012). Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl. Australian Journal of Chemistry, 65(7), 730.
Permanent Research Commons link: https://hdl.handle.net/10289/6819
The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.