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      Crystal structure of (η⁵ pentamethylcyclopentadienyl){bis(pentafluorophenyl)×thiomethylphenyl phosphine-κ₂ S,P)chloro-iridium(III) tetrafluoroborate

      Bellabarba, R. M.; Nieuwenhuyzen, Mark; Saunders, Graham C.
      DOI
       10.1134/S0022476613020315
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      Bellabarba, R.M., Nieuwenhuyzen, M., & Saunders, G. C. (2013). Crystal structure of (η⁵ pentamethylcyclopentadienyl){bis(pentafluorophenyl)×thiomethylphenyl phosphine-κ₂ S,P)chloro-iridium(III) tetrafluoroborate. Journal of Stractural Chemistry, 54(2), 471-473.
      Permanent Research Commons link: https://hdl.handle.net/10289/7869
      Abstract
      The salt (η⁵-pentamethylcyclopentadienyl){bis(pentafluorophenyl)thiomethylphenylphosphine-κ₂ S,P)chloroiridium(III) tetrafluoroborate, [(η⁵-C₅Me₅)IrCl{κ₂ S,P-(C₆F₅)₂PC₆H₄SMe-2}]BF₄, crystallizes as a conglomerate in the orthorhombic crystal system in space group P2₁2₁2₁ with unit cell parameters a = 9.9621(9) Å, b = 16.7793(15) Å, c = 18.5040(16) Å, V = 3093.1(5) ų, Z = 4, d calc = 2.014 g•cm⁻³. The structure of the S Ir, S S stereoisomer reveals three-legged piano stool geometry about Ir, with Cp*-Ir, Ir-P, Ir-S and Ir-Cl distances of 1.847(5) Å, 2.2791(14) Å, 2.3451(13) Å, and 2.3840(12) Å respectively.
      Date
      2013
      Type
      Journal Article
      Publisher
      Springer
      Collections
      • Science and Engineering Papers [3011]
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