Show simple item record  

dc.contributor.authorNicholson, Brian K.
dc.contributor.authorWilson, Peter S.
dc.contributor.authorNancekivell, Adelle
dc.date.accessioned2013-09-26T23:27:09Z
dc.date.available2013-09-26T23:27:09Z
dc.date.copyright2013-11
dc.date.issued2013
dc.identifier.citationNicholson, B. K., Wilson, P. S., & Nancekivell, A. (2013). A re-investigation of arsenoacetic acid, (AsCH₂COOH)n. Journal of Organometallic Chemistry, 745-746, 80-85.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/8028
dc.description.abstractDetailed spectroscopic data have been obtained for arsonoacetic acid, As(CH₂COOH)O₃H₂, and its barium and sodium salts. The X-ray crystal structure of the free acid is isomorphous with phosphonoacetic acid. Reduction gave the As(I) compound arsenoacetic acid, (AsCH₂COOH)n which was shown by ESI-MS to contain cyclic species based on As–As bonds, with n mainly 3–6. The X-ray crystal structure of the hexamer was determined as the pyridine solvate and shown to have a hexacyclic As₆ ring in a puckered chair conformation, with –CH₂COOH groups in equatorial sites, each H-bonded to a pyridine molecule in the lattice.en_NZ
dc.language.isoenen_NZ
dc.publisherElsevieren_NZ
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.urihttp://www.sciencedirect.com/science/article/pii/S0022328X13005639en_NZ
dc.titleA re-investigation of arsenoacetic acid, (AsCH₂COOH)nen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.jorganchem.2013.07.056en_NZ
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page80en_NZ
pubs.elements-id38755
pubs.end-page85en_NZ
pubs.volume745-746en_NZ


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record