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dc.contributor.authorNicholson, Brian K.
dc.contributor.authorClark, Christopher J.
dc.contributor.authorJameson, Geoffrey B.
dc.contributor.authorTelfer, Shane G.
dc.date.accessioned2013-09-27T03:36:51Z
dc.date.available2013-09-27T03:36:51Z
dc.date.copyright2013-09
dc.date.issued2013
dc.identifier.citationNicholson, B. K., Clark, C. J., Jameson, G. B., & Telfer, S. G. (2013). Rubidium-templated bowl-shaped isopolyoxoantimonates [RbH₁₁-ₓ(RSb)₁₄O₃₄]ₓ- derived from arylstibonic acids. Inorganica Chimica Acta, 406, 53-58.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/8030
dc.description.abstractArylstibonic acids, RSbO₃H₂ (R = p-MeC₆H₄- or p-ClC₆H₄-) when neutralised in the presence of Rb⁺ give isopolyoxometalates derived from [RbH₁₁(RSb) ₁₄O₃₄]. The X-ray crystal structures of four examples were determined and all gave the same basic framework with a bowl-shaped Sb14 polyhedron cradling the Rb⁺ in an 11-coordinate embrace. All were further linked into chains in the lattice by an intermolecular interaction involving a second Rb⁺, coordinated to three O atoms of one polyoxometalate and to an aryl group of an adjacent unit via an η⁶ interaction. One example has the same basic structure but with one framework O atom replaced by a Br.en_NZ
dc.language.isoenen_NZ
dc.publisherElsevieren_NZ
dc.relation.ispartofInorganica Chimica Acta
dc.relation.urihttp://www.sciencedirect.com/science/article/pii/S0020169313003575en_NZ
dc.subjectPolyoxometalatesen_NZ
dc.subjectantimonyen_NZ
dc.subjectrubidiumen_NZ
dc.subjectcrystal structureen_NZ
dc.subjectelectrospray ionisation mass spectrometryen_NZ
dc.titleRubidium-templated bowl-shaped isopolyoxoantimonates [RbH₁₁˗ₓ(RSb)₁₄O₃₄]ₓ˗ derived from arylstibonic acidsen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.ica.2013.06.034en_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page53en_NZ
pubs.elements-id38838
pubs.end-page58en_NZ
pubs.volume406en_NZ
uow.identifier.article-noCen_NZ


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