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dc.contributor.authorDevoy, Sarah M.
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2013-09-27T04:03:09Z
dc.date.available2013-09-27T04:03:09Z
dc.date.copyright2013-09
dc.date.issued2013
dc.identifier.citationDevoy, S. M., Henderson, W., & Nicholson, B. K. (2013). Dinuclear platinum(II) complexes containing ferrocenylalkyl–thiolate and –selenolate ligands. Inorganica Chimica Acta, 406, 81-86.en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/8031
dc.description.abstractAlkylation reactions of [Pt₂(μ-S)₂(PPh₃)₄] with haloalkylferrocenes FcCH₂Cl, Fc(CH₂)₆Br and Fc(CH₂)₁₁Br [Fc = (η⁵-C₅H₅)Fe(η⁵-C₅H₄)] gave the cationic μ-thiolate complexes [Pt₂(μ-S){μ-S(CH₂)nFc}(PPh₃)₄]⁺ (n = 1, 6, 11), isolated as PF₆⁻ and/or BPh₄⁻ salts, and characterised by ESI mass spectrometry, NMR spectroscopy, microelemental analysis, and by an X-ray structure determination on [Pt₂(μ-S){μ-SCH₂Fc}(PPh₃)₄]PF₆. The complex contains the typical folded {Pt₂(μ-S)₂} core with an axial ferrocenylmethylthiolate ligand. The corresponding selenolate complex [Pt₂ (μ-Se){μ-SeCH₂Fc}(PPh₃)₄]⁺ was similarly obtained by alkylation of [Pt₂(μ-Se)₂ (PPh₃)₄] with FcCH₂Cl, and isolated as PF₆⁻ and BPh₄⁻ salts. The attempted liberation of FcCH₂SH from [Pt₂(μ-S){μ-SCH₂Fc}(PPh₃)₄]+ using Na₂S was not successful.en_NZ
dc.language.isoenen_NZ
dc.publisherElsevieren_NZ
dc.relation.ispartofInorganica Chimica Acta
dc.relation.urihttp://www.sciencedirect.com/science/article/pii/S0020169313003757en_NZ
dc.subjectthiolateen_NZ
dc.subjectselenolateen_NZ
dc.subjectferrocene compoundsen_NZ
dc.subjectplatinum complexesen_NZ
dc.subjectX-ray crystal structureen_NZ
dc.titleDinuclear platinum(II) complexes containing ferrocenylalkyl–thiolate and –selenolate ligandsen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.ica.2013.07.004en_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page81en_NZ
pubs.elements-id38839
pubs.end-page86en_NZ
pubs.volume406en_NZ
uow.identifier.article-noCen_NZ


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