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Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆

Abstract
Reaction of cyclomanganated aryl ketones with CS₂ proceeds with insertion into the Mn–C bond to give η²-dithiocarboxylato–Mn(CO)₄ compounds. With other cyclomanganated substrates such as that from Ph₃P=S and also with Mn₂(CO)₁₀, CS₂ gives (μ₃-CS₃)₂Mn₄(CO)₁₆ with bridging trithiocarbonate ligands.
Type
Journal Article
Type of thesis
Series
Citation
Mace, W.J., Main, L., Nicholson, B.K & Hagyard, M.L. (2002). Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆. Journal of Organometallic Chemistry, 664, 288-293.
Date
2002-01-01
Publisher
Elsevier SA
Degree
Supervisors
Rights
This is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V.