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Sulfide-bridged aggregates from the metalloligand [Pt₂(μ-S)₂(PPh₃)₄] and β-diketonate complexes of cobalt(II) and zinc(II)

Abstract
Reaction of [Pt₂(μ-S)₂(PPh₃)₄] with a range of zinc(II) and cobalt(II) complexes ML₂, where L is a β-diketonate ligand CH₃COCHCOCH₃, PhCOCHCOPh, CF₃COCHCOTh (Th = 2-thienyl)] permits the synthesis of adducts [Pt₂(μ-S)₂(PPh₃)₄M(diketonate)]⁺, isolated as their BPH₄⁻salts in moderate yields. The cobalt and zinc acetylacetonate complexes were characterised by single-crystal X-ray diffraction studies, which reveal isomorphous structures, with tetrahedral heterometal centres.
Type
Journal Article
Type of thesis
Series
Citation
Bridson, J.H., Henderson, W., Nicholson, B.K. & Hor, T.S.A. (2006). Sulfide-bridged aggregates from the metalloligand [Pt₂(μ-S)₂(PPh₃)₄] and β-diketonate complexes of cobalt(II) and zinc(II). Inorganica Chimica Acta, 359(2), 680-684.
Date
2006-01-01
Publisher
Elsevier BV
Degree
Supervisors
Rights
This article is published in the journal Inorganica Chimica Acta, (c) 2005 Elsevier B.V.