Lloyd, Nicholas C.Nicholson, Brian K.2009-07-172009-07-172007Lloyd, N. C. & Nicholson, B. K. (2007). cyclo-Tetra-μ-oxido-tetrakis[3-nitro-4-hydroxyphenylarsenic(III)]. Acta Crystallographica Section E, 63(10), 1-11.https://hdl.handle.net/10289/2687The title compound, [As₄O₄(C₆H₄NO₃)₄], has an eight-membered As₄O₄ ring with a slightly twisted boat-chair conformation. The aryl groups complete the threefold coordination for each As atom. Each OH group forms a strong intramolecular O-H⋯O hydrogen bond to the adjacent NO₂ group, with only weak C-H⋯O, O⋯As [3.036 (6)-3.184 (6) Å] and O⋯O [2.921 (10)-2.930 (10) Å] interactions between tetramers.application/pdfenThis is an electronic reprint as authorised by the publisher.metal-organic compoundchemistryJournal Articledoi:10.1107/S1600536807044728