Henderson, WilliamLeach, Meto T.Nicholson, Brian K.Sabat, Michal2010-10-142010-10-141995Henderson, W., Leach, M.T., Nicholson, B.K. & Sabat, M. (1995). Self-assembly of a columnar polymeric calcium phosphinate derived from camphene. Journal of the Chemical Society, Dalton Transactions, 12, 2109-2110.https://hdl.handle.net/10289/4697(2,2-Dimethylbicyclo[2.2.1] hept-3-ylmethyl)phosphinic acid (RPO₂H₂), readily prepared from camphene and hypophosphorous acid, formed a polymeric calcium salt [{Ca(RPO₂H) ₂ (RPO₂H₂)(H₂O)}n], with both terminal and triply bridging phosphinate groups, and an overall columnar structure with an inorganic core and a pseudo-close-packed sheath of terpene moieties.application/pdfenThis article has been published in Journal of the Chemical Society, Dalton Transactions. © 1995 The Royal Society of Chemistry.chemistryJournal Article10.1039/DT9950002109