Dai, YuanNicholson, Brian K.2012-11-082012-11-0820122012Dai, Y., & Nicholson, B. K. (2012). Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl. Australian Journal of Chemistry, 65(7), 730.0004-9425https://hdl.handle.net/10289/6819The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.endimeric complexessulfur atomsthioglycolateJournal Article10.1071/CH11395