Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆

Mace, WadeMain, LyndsayNicholson, Brian K.Hagyard, Marion2008-03-192007-08-282008-03-192002-01-01Mace, W.J., Main, L., Nicholson, B.K & Hagyard, M.L. (2002). Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆. Journal of Organometallic Chemistry, 664, 288-293.https://hdl.handle.net/10289/212Reaction of cyclomanganated aryl ketones with CS₂ proceeds with insertion into the Mn–C bond to give η²-dithiocarboxylato–Mn(CO)₄ compounds. With other cyclomanganated substrates such as that from Ph₃P=S and also with Mn₂(CO)₁₀, CS₂ gives (μ₃-CS₃)₂Mn₄(CO)₁₆ with bridging trithiocarbonate ligands.application/pdfenThis is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V.Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆Journal Article10.1016/S0022-328X(02)02024-7