Ennis, Courtney P.Lane, Joseph R.Kjaergaard, Henrik G.McKinley, Allan J.2009-08-242009-08-242009Ennis, C. P., Lane, J. R., Kjaergarrd, H. G. & McKinley, A. J. (2009). Identification of the water amidogen radical complex. Journal of the American Chemical Society, 131(4), 1358-1358.https://hdl.handle.net/10289/2858The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.enchemistryJournal Article10.1021/ja808109m