A six-coordinate aryl-germanium complex formed by the Kläui ligand
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This is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2007 Elsevier B.V.
Abstract
PhGeCl₃ reacts with Na{[OP(OEt)₂]₃CoCp} to give the six-coordinate complex PhCl₂Ge{[OP(OEt)₂]₃CoCp}, characterised spectroscopically and by an X-ray crystal structure determination which showed a firmly-attached tridentate ligand [Ge–O 1.973(2) Å].
Citation
Davidson, K.A., Kilpin, K.J., Lloyd, N.J. & Nicholson, B.K. (2007) A six-coordinate aryl-germanium complex formed by the Klui ligand. Journal of Organometallic Chemistry, 692, 1871-1874.
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Elsevier