Publication: A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone
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Abstract
Reaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.
Citation
Ujam, O. T., Henderson, W. & Nicholson, B. K. (2013). A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone. Journal of Structural Chemisty, 54(3), 523-527.
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Springer