Anomalous reaction of an aryl silane with Co₂ (CO)₂; characterisation of Me ₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂
Harfoot, G.J. & Nicholson, B.K. (2003). Anomalous reaction of an aryl silane with Co2(CO)8; characterisation of Me2NC6H4Si[Co(CO)4][OCCo3(CO)9]2. Journal of Organometallic Chemistry, 669, 106-108.
Permanent Research Commons link: https://hdl.handle.net/10289/220
Reaction of Me₂NC₆H₄SiH₃ with Co₂(CO)₈ gave Me₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂ which was shown to have one –Co(CO)₄ group and two –OCCo₃(CO)₉ cluster units bonded to the silicon atom.
This is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2003 Elsevier Science B.V.