Anomalous reaction of an aryl silane with Co₂ (CO)₂; characterisation of Me ₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂

Harfoot, Gwion J.; Nicholson, Brian K.

doi:10.1016/S0022-328X(02)02224-6

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Harfoot, G.J. & Nicholson, B.K. (2003). Anomalous reaction of an aryl silane with Co2(CO)8; characterisation of Me2NC6H4Si[Co(CO)4][OCCo3(CO)9]2. Journal of Organometallic Chemistry, 669, 106-108.

Permanent Research Commons link: https://hdl.handle.net/10289/220

Abstract

Reaction of Me₂NC₆H₄SiH₃ with Co₂(CO)₈ gave Me₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂ which was shown to have one –Co(CO)₄ group and two –OCCo₃(CO)₉ cluster units bonded to the silicon atom.

Date

2003-01-01

Type

Journal Article

Publisher

Elsevier S.A.

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Science and Engineering Papers [3124]