Iron(III) complexes of the metalloligand [Pt2(μ-S)2(PPh3)4]

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dc.contributor.authorHenderson, William
dc.contributor.authorOliver, Allen G.
dc.contributor.authorTurnbull, Mark M.
dc.date.accessioned2013-01-15T22:55:44Z
dc.date.available2013-01-15T22:55:44Z
dc.date.copyright2013-01
dc.date.issued2013
dc.description.abstractReaction of [Pt₂(μ-S)₂(PPh₃) ₄] with (NH₄)₂SO₄•FeSO ₄•6H₂O and 2 mol equivalents of picolinic acid (HPic) or 8-hydroxyquinoline (HQ) and trimethylamine base gives iron(III) adducts [Pt₂(μ-S)₂(PPh₃) ₄FePic2]+ and [Pt₂(μ-S) ₂(PPh₃)₄FeQ₂]+, isolated as hexafluorophosphate salts; these complexes are the first isolated iron(III) derivatives of [Pt₂(μ-S)₂(PPh₃) ₄]. The X-ray structure of [Pt₂(μ-S) ₂(PPh₃)₄FePic2]PF6 shows the presence of a rare distorted trigonal prismatic coordination geometry while magnetic measurements confirm the presence of high-spin iron(III) centres in the complexes.en_NZ
dc.identifier.citationHenderson, W., Oliver, A. G., & Turnbull, M. M. (2013). Iron(III) complexes of the metalloligand [Pt2(μ-S)2(PPh3)4]. Inorganic Chemistry Communications, 27, 142-145.en_NZ
dc.identifier.doi10.1016/j.inoche.2012.10.027en_NZ
dc.identifier.issn1387-7003
dc.identifier.urihttps://hdl.handle.net/10289/7063
dc.language.isoen
dc.publisherElsevieren_NZ
dc.relation.isPartOfInorganic Chemistry Communicationsen_NZ
dc.relation.ispartofInorganic Chemistry Communications
dc.subjectCrystal structureen_NZ
dc.subjectElectrospray ionisation mass spectrometryen_NZ
dc.subjectIron complexesen_NZ
dc.subjectPlatinum complexesen_NZ
dc.titleIron(III) complexes of the metalloligand [Pt2(μ-S)2(PPh3)4]en_NZ
dc.typeJournal Articleen_NZ
dspace.entity.typePublication
pubs.begin-page142en_NZ
pubs.end-page145en_NZ
pubs.volume27en_NZ
uow.identifier.article-noCen_NZ
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