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Stable oxygen and carbon isotope compositional fields for skeletal and diagenetic components in New Zealand Cenozoic nontropical carbonate sediments and limestones: A synthesis and review

Abstract
The stable oxygen isotope composition (δ18O) of a precipitated carbonate depends mainly on the isotope composition, salinity, and temperature of the host fluid, whereas the stable carbon isotope composition (δ13C) reflects the source of CO2 for precipitation, such as meteoric or sea water, shell dissolution, or various biochemical origins, including microbial oxidation of organic matter and methane. Despite the potentially complex array of controls, natural waters tend to show a characteristic range of isotope values which in turn are mimicked or tracked by the carbonate minerals precipitated from them. Consequently, plots of δ18O versus δ13C for carbonate materials can help identify their depositional and/or diagenetic environment(s). Here we compile isotope results for about 800 samples of carbonate skeletons, bulk sediments, fossils, limestones, cements, concretions, and veins spanning a range of ages (latest Cretaceous to modern) and locations in temperate-region New Zealand. Despite some overlap, the isotope values for 21 defined categories of carbonate materials tend to group in discrete regions of the δ18O-δ13C diagram, thereby providing important insights about their origin. New Zealand modern skeletal shelf carbonates plot in a distinctly different field from their tropical counterparts because of their heavier δ18O and narrower range of δ13C values, in accord with their nontropical bryomol skeletal facies. Cements in New Zealand temperate limestones are predominantly of burial or, more rarely, meteoric origin, but their nontropical heritage based solely on isotope composition becomes blurred and eventually lost as diagenesis proceeds. In common with many other global examples, siderite, calcite, and dolomite concretions have developed during shallow burial in a range of freshwater to marine depositional settings, the carbon originating mainly from early diagenetic, bacterially mediated reactions involving the decomposition of organic matter in bottom sediments. A summary δ18O-δ13C diagram showing mean and standard-deviation isotope values for the various New Zealand carbonate categories will form a basis for comparing and interpreting other carbonate materials and deposits. © 1996 Taylor & Francis Group, LLC.
Type
Journal Article
Type of thesis
Series
Citation
Nelson, C. S., & Smith, A. M. (1996). Stable oxygen and carbon isotope compositional fields for skeletal and diagenetic components in New Zealand Cenozoic nontropical carbonate sediments and limestones: A synthesis and review. New Zealand Journal of Geology, and Geophysics, 39(1), 93-107. https://doi.org/10.1080/00288306.1996.9514697
Date
1996-01-01
Publisher
Degree
Supervisors
Rights
This article has been published in the journal: New Zealand Journal of Geology and Geophysics. © 1996 The Royal Society of New Zealand.