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dc.contributor.authorHenderson, Williamen_NZ
dc.contributor.authorOkpareke, Obinna C.en_NZ
dc.contributor.authorAzizan, Ainnul Hamidah Syahadahen_NZ
dc.contributor.authorTiekink, Edward R. T.en_NZ
dc.date.accessioned2019-07-22T02:18:01Z
dc.date.available2019en_NZ
dc.date.available2019-07-22T02:18:01Z
dc.date.issued2019en_NZ
dc.identifier.citationHenderson, W., Okpareke, O. C., Azizan, A. H. S., & Tiekink, E. R. T. (2019). [Dicyclohexyl(sulfanylidene)-λ⁵-phosphanyl]methanol. Molbank, 2019(3), M1069–M1069. https://doi.org/10.3390/m1069en
dc.identifier.urihttps://hdl.handle.net/10289/12714
dc.description.abstractThe title compound, [dicyclohexyl(sulfanylidene)-λ⁵-phosphanyl]methanol, Cy₂P(=S)CH₂OH (1), was obtained from the reaction between [Cy₂P(CH₂OH)₂]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray structure determination as well as IR, and ¹D-NMR (¹H, ¹³C{1H}, ³¹P{1H}), and 2D-NMR (DEPT-135 and HSQC) spectroscopy, ESI mass spectrometry, and elemental analysis. X-ray crystallography on Compound 1 shows the phosphorus atom to be tetrahedrally coordinated within a non-symmetric C₃S donor set but with relatively minor distortions from the ideal geometry. In the molecular packing, hydroxyl-O–H⋯S(thione) hydrogen bonds led to supramolecular helical chains along the b-axis direction.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherMDPI AGen_NZ
dc.relation.urihttps://www.mdpi.com/1422-8599/2019/3/M1069en_NZ
dc.rightsThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
dc.subjectphosphane sulfideen_NZ
dc.subjecthydrogen bondingen_NZ
dc.subjectESI mass spectrometryen_NZ
dc.subjectX-ray crystallographyen_NZ
dc.title[Dicyclohexyl(sulfanylidene)-λ⁵-phosphanyl]methanolen_NZ
dc.typeJournal Article
dc.identifier.doi10.3390/m1069en_NZ
dc.relation.isPartOfMolbanken_NZ
pubs.begin-pageM1069
pubs.elements-id238765
pubs.end-pageM1069
pubs.issue3en_NZ
pubs.volume2019en_NZ
dc.identifier.eissn1422-8599en_NZ


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