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dc.contributor.authorHenderson, Williamen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.date.accessioned2008-03-19T05:08:14Z
dc.date.available2007-11-14en_US
dc.date.available2008-03-19T05:08:14Z
dc.date.issued2003-03-01en_US
dc.identifier.citationHenderson, W. & Nicholson, B.K. (2003). Hydrogen-bonded adducts formed from platinum(II) and palladium(II) thiosalicylate complexes [(Ph₃E)₂M(SC₆H₄CO₂)] (E=P, As) and triethylammonium or pyridinium ions; X-ray crystal structure of [(Ph₃P)₂Pt(SC₆H₄CO₂) HNEt₃]⁺[BPh₄]⁻. Inorganica Chimica Acta 346, 7-11.en_US
dc.identifier.urihttps://hdl.handle.net/10289/138
dc.description.abstractOne-pot reactions of [MCl₂(cod)] (cod=cyclo-octa-1,5-diene; M=Pt, Pd) with two equiv of PPh₃ or AsPh₃, one equiv of thiosalicylic acid, and an excess of triethylamine base, followed by the addition of excess Na[BPh₄] to the hot reaction mixture gives complexes [(Ph₃E)₂M(SC₆H₄CO₂) HNEt₃]⁺[BPh4]⁻ (E=P, As). Analogous pyridinium and platinum–thioglycolate [(Ph₃P)₂Pt(SCH₂CO₂)] derivatives were also prepared. An X-ray crystal structure determination on [(Ph₃P)₂Pt(SC₆H₄CO₂) HNEt₃]⁺[BPh₄]⁻ reveals hydrogen-bonding between the NH proton and the carbonyl group of the thiosalicylate ligand, the major effect of which is to flatten the platinum–thiosalicylate moiety. NMR spectroscopic data indicate that the hydrogen-bonding interaction persists in solution.en_US
dc.language.isoen
dc.publisherElsevier BVen_NZ
dc.subjectpalladium(II) thiosalicylate complexesen_US
dc.subjectCrystal structuresen_US
dc.titleHydrogen-bonded adducts formed from platinum(II) and palladium(II) thiosalicylate complexes [(Ph₃E)₂M(SC₆H₄CO₂)] (E=P, As) and triethylammonium or pyridinium ions; X-ray crystal structure of [(Ph₃P)₂Pt(SC₆H₄CO₂) HNEt₃]⁺[BPh₄]⁻en_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1016/S0020-1693(02)01380-4en_US
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page7en_NZ
pubs.editionMarchen_NZ
pubs.elements-id29322
pubs.end-page11en_NZ
pubs.volume346en_NZ
uow.identifier.article-noPII S0020-1693(02)01380-4en_NZ


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