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dc.contributor.authorMcIndoe, J. Scotten_US
dc.contributor.authorNicholson, Brian K.en_US
dc.date.accessioned2008-03-19T05:08:00Z
dc.date.available2007-08-28en_US
dc.date.available2008-03-19T05:08:00Z
dc.date.issued2002-01-01en_US
dc.identifier.citationMcIndoe, J.S. & Nicholson, B.K. (2002). New complexes with M-Si-O or M-Si-S linkages (M = Fe, Co). Journal of Organometallic Chemistry, 648, 237-245.en_US
dc.identifier.urihttps://hdl.handle.net/10289/144
dc.description.abstractPh2XSiFe(CO)2Cp [X = p-tolylS (1a), MeO (1b)] and Ph[2-MeOC6H4]XSiFe(CO)2Cp [X = Cl (2a), OMe (2b)] have been fully characterised, including X-ray crystal structure determinations for 1a, 1b and 2a. None of the examples showed any tendency for migration of the X groups from silicon to iron, with elimination of silylene. However very ready loss of the X groups was seen in the electrospray mass spectra, suggesting formation of the cationic silylene-iron complex ions is favoured. This was especially so for 2a and 2b, where intramolecular stabilisation of the silicon centre from the 2-OMe group is possible.The stable siloxane O[SiPh2{Co(CO)4}]2 was also characterised; the X-ray crystal structure analysis shows a Si-O-Si bond angle of 153°.en_US
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevier SAen_NZ
dc.relation.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#descriptionen_US
dc.rightsThis is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V.en_US
dc.titleNew complexes with M-Si-O or M-Si-S linkages (M = Fe or Co)en_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1016/S0022-328X(01)01403-6en_US
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page237en_NZ
pubs.elements-id27493
pubs.end-page245en_NZ
pubs.issue1-2en_NZ
pubs.volume648en_NZ


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