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dc.contributor.authorEvans, David J.en_US
dc.contributor.authorHitchcock, Peter B.en_US
dc.contributor.authorLeigh, G. Jeffreyen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.contributor.authorNiedwieski, Antonio C.en_US
dc.contributor.authorNunes, Fabio S.en_US
dc.contributor.authorSoares, Jaisa F.en_US
dc.identifier.citationEvans, D.J., Hitchcock, P.B., Leigh, G.J., Nicholson, B.K., Niedwieski, A.C., Nunes, F.S. & Soares, J.F. (2001). The synthesis of triangulo-trimetal complexes containing both iron(II) and vanadium(II). Inorganica Chimica Acta 319, 147-158.en_US
dc.description.abstractReactions between a variety of vanadium(II) and iron(II) starting materials in tetrahydrofuran (thf) solution afforded di-, tri-, and tetra-nuclear complexes containing thf or N,N,N′,N′-tetramethylethylenediamine (tmen) as ligands. Most products were ionic and contained the two metals in different structural units, cation or anion. Trinuclear clusters formulated as [V3−xFexCl₅(tmen)₃][BPh₄](x=0–3) were obtained and characterised by C, H, N and metal analyses, ¹H NMR, Mössbauer, and positive ion FAB and electrospray mass spectroscopies, and magnetic moment measurements in solution. We characterised fully by low-temperature single-crystal X-ray diffraction analysis the mixed-metal triangulo-complex salt [V₂Fe(μ-Cl)₃(μ₃-Cl)₂(tmen)₃][BPh₄].en_US
dc.publisherElsevier Science B.V.en_NZ
dc.rightsThis article is published in the journal Inorganica Chimica Acta, (c) 2001 Elsevier Science B.V.en_US
dc.subjectCrystal structuresen_US
dc.subjectIron(II) complexesen_US
dc.subjectVanadium(II) complexesen_US
dc.subjectTriangulo-trimetal complexesen_US
dc.titleThe synthesis of triangulo-trimetal complexes containing both iron(II) and vanadium(II)en_US
dc.typeJournal Articleen_US
dc.relation.isPartOfInorganica Chimica Actaen_NZ

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