| dc.contributor.author | Evans, Cameron | en_US |
| dc.contributor.author | Nicholson, Brian K. | en_US |
| dc.date.accessioned | 2008-03-19T05:08:11Z | |
| dc.date.available | 2007-11-22 | en_US |
| dc.date.available | 2008-03-19T05:08:11Z | |
| dc.date.issued | 2003-01-01 | en_US |
| dc.identifier.citation | Evans, C. & Nicholson, B.K. (2003). Isonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄. Journal of Organometallic Chemistry, 665(1-2), 95-100. | en_US |
| dc.identifier.uri | https://hdl.handle.net/10289/167 | |
| dc.description.abstract | The substitution of carbonyl ligands by isonitriles on Co₄(μ₄-SiC₆H₄R)₂(CO)₁₁ (R=H, OMe, NMe₂) clusters has been examined. The reactions could be monitored by electrospray ionisation mass spectrometry, identifying the substituted products as either protonated [M+H]⁺ (R=NMe₂) or oxidised [M]⁺ (R=H, OMe) ions. Evidence for substitution of up to nine carbonyl ligands was found and the structure of tetra-substituted example, Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄, was determined. | en_US |
| dc.language.iso | en | |
| dc.publisher | Elsevier S.A. | en_NZ |
| dc.rights | This article is published in the Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V. | en_US |
| dc.subject | Cluster | en_US |
| dc.subject | Electrospray mass spectrometry | en_US |
| dc.subject | Isonitrile | en_US |
| dc.subject | Crystal structure determination | en_US |
| dc.title | Isonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄ | en_US |
| dc.type | Journal Article | en_US |
| dc.identifier.doi | 10.1016/S0022-328X(02)02068-5 | en_US |
| dc.relation.isPartOf | Journal of Organometallic Chemistry | en_NZ |
| pubs.begin-page | 95 | en_NZ |
| pubs.edition | January | en_NZ |
| pubs.elements-id | 29321 | |
| pubs.end-page | 100 | en_NZ |
| pubs.issue | 1-2 | en_NZ |
| pubs.volume | 665 | en_NZ |
