Research Commons
      • Browse 
        • Communities & Collections
        • Titles
        • Authors
        • By Issue Date
        • Subjects
        • Types
        • Series
      • Help 
        • About
        • Collection Policy
        • OA Mandate Guidelines
        • Guidelines FAQ
        • Contact Us
      • My Account 
        • Sign In
        • Register
      View Item 
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      JavaScript is disabled for your browser. Some features of this site may not work without it.

      Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules

      Mace, Wade; Main, Lyndsay; Nicholson, Brian K.; van de Pas, Daniel J.
      Thumbnail
      Files
      content.pdf
      381.6Kb
      DOI
       10.1016/j.jorganchem.2004.04.042
      Link
       www.elsevier.com
      Find in your library  
      Citation
      Export citation
      Mace, W.J., Main, L., Nicholson, B.K. & van de Pas, D.J. (2004). Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules. Journal of Organometallic Chemistry, 689, 2523-2530.
      Permanent Research Commons link: https://hdl.handle.net/10289/174
      Abstract
      Reaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC≡CH, CH2=CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-η⁵-azacyclohexadienyl-Mn(CO)₃ complex from the reaction with the alkyne.

      PhCH₂Mn(CO)₅ reacts with l,4-di-aryl-1-aza-1,3-butadienes in the presence of unsaturated substrates to give products based on a cyclomanganated intermediate.
      Date
      2004-08-01
      Type
      Journal Article
      Publisher
      Elsevier SA
      Rights
      This is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2004 Elsevier Science B.V.
      Collections
      • Science and Engineering Papers [3019]
      Show full item record  

      Usage

      Downloads, last 12 months
      52
       
       
       

      Usage Statistics

      For this itemFor all of Research Commons

      The University of Waikato - Te Whare Wānanga o WaikatoFeedback and RequestsCopyright and Legal Statement