dc.contributor.author | Henderson, William | en_US |
dc.contributor.author | Evans, Cameron | en_US |
dc.contributor.author | Nicholson, Brian K. | en_US |
dc.contributor.author | Fawcett, John | en_US |
dc.date.accessioned | 2008-03-19T05:08:09Z | |
dc.date.available | 2007-11-14 | en_US |
dc.date.available | 2008-03-19T05:08:09Z | |
dc.date.issued | 2003-01-01 | en_US |
dc.identifier.citation | Henderson, W., Evans, C., Nicholson, B. K. & Fawcett, J. (2003). Coordination isomerism in salicylhydroxamate complexes of platinum(II) and palladium(II). Dalton Transactions (13), 2691-2697. | en_US |
dc.identifier.uri | https://hdl.handle.net/10289/194 | |
dc.description.abstract | The syntheses of a range of platinum(II) and palladium(II) complexes containing salicylhydroxamate ligands are described. The ancillary ligands, together with the synthetic route, influence the coordination mode of the salicylhydroxamate ligand. Reaction of cis-[PtCl₂(PPh₃)₂] with salicylhydroxamic acid and trimethylamine in hot methanol gave O,O′-bonded [Pt{OC( NO)C₆H₄OH}(PPh₃)₂], but [PtCl₂(cod)](cod = cycloocta-1,5-diene) gave N,O-bonded [Pt{OC₆H₄C(O)NOH}(cod)]. Ligand substitution gives other N,O bonded complexes, including [Pt{OC₆H₄C(O)NOH}(PPh₃)₂]. Reaction of K₂PtCl₄ with 2 equiv. of EPh₃(E = As or Sb), salicylhydroxamic acid and excess trimethylamine gives products whose structures depend on E; AsPh₃ gives [Pt{OC( NO)C₆H₄OH}(AsPh₃)₂], while SbPh₃ gives [Pt{OC₆H₄C(O)NOH}(SbPh₃)₂]. | en_US |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | en_NZ |
dc.relation.uri | http://www.rsc.org.ezproxy.waikato.ac.nz:2048/Publishing/Journals/DT/article.asp?doi=b303367h | en_US |
dc.rights | This article is published in the journal Dalton Transactions, (c) Royal Society of Chemistry 2003 | en_US |
dc.subject | Platinum(II) complexes; palladium(II) thiosalicylate complexes; Crystal structures | en_US |
dc.title | Coordination isomerism in salicylhydroxamate complexes of platinum(II) and palladium(II) | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1039/b303367h | en_US |
dc.relation.isPartOf | Dalton Transactions | en_NZ |
pubs.begin-page | 2691 | en_NZ |
pubs.elements-id | 29256 | |
pubs.end-page | 2697 | en_NZ |
pubs.issue | 13 | en_NZ |
pubs.volume | 13 | en_NZ |