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dc.contributor.authorHenderson, Williamen_US
dc.contributor.authorEvans, Cameronen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.contributor.authorFawcett, Johnen_US
dc.date.accessioned2008-03-19T05:08:09Z
dc.date.available2007-11-14en_US
dc.date.available2008-03-19T05:08:09Z
dc.date.issued2003-01-01en_US
dc.identifier.citationHenderson, W., Evans, C., Nicholson, B. K. & Fawcett, J. (2003). Coordination isomerism in salicylhydroxamate complexes of platinum(II) and palladium(II). Dalton Transactions (13), 2691-2697.en_US
dc.identifier.urihttps://hdl.handle.net/10289/194
dc.description.abstractThe syntheses of a range of platinum(II) and palladium(II) complexes containing salicylhydroxamate ligands are described. The ancillary ligands, together with the synthetic route, influence the coordination mode of the salicylhydroxamate ligand. Reaction of cis-[PtCl₂(PPh₃)₂] with salicylhydroxamic acid and trimethylamine in hot methanol gave O,O′-bonded [Pt{OC( NO)C₆H₄OH}(PPh₃)₂], but [PtCl₂(cod)](cod = cycloocta-1,5-diene) gave N,O-bonded [Pt{OC₆H₄C(O)NOH}(cod)]. Ligand substitution gives other N,O bonded complexes, including [Pt{OC₆H₄C(O)NOH}(PPh₃)₂]. Reaction of K₂PtCl₄ with 2 equiv. of EPh₃(E = As or Sb), salicylhydroxamic acid and excess trimethylamine gives products whose structures depend on E; AsPh₃ gives [Pt{OC( NO)C₆H₄OH}(AsPh₃)₂], while SbPh₃ gives [Pt{OC₆H₄C(O)NOH}(SbPh₃)₂].en_US
dc.language.isoen
dc.publisherRoyal Society of Chemistryen_NZ
dc.relation.urihttp://www.rsc.org.ezproxy.waikato.ac.nz:2048/Publishing/Journals/DT/article.asp?doi=b303367hen_US
dc.rightsThis article is published in the journal Dalton Transactions, (c) Royal Society of Chemistry 2003en_US
dc.subjectPlatinum(II) complexes; palladium(II) thiosalicylate complexes; Crystal structuresen_US
dc.titleCoordination isomerism in salicylhydroxamate complexes of platinum(II) and palladium(II)en_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1039/b303367hen_US
dc.relation.isPartOfDalton Transactionsen_NZ
pubs.begin-page2691en_NZ
pubs.elements-id29256
pubs.end-page2697en_NZ
pubs.issue13en_NZ
pubs.volume13en_NZ


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