Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆

Mace, Wade; Main, Lyndsay; Nicholson, Brian K.; Hagyard, Marion

doi:10.1016/S0022-328X(02)02024-7

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Mace, W.J., Main, L., Nicholson, B.K & Hagyard, M.L. (2002). Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆. Journal of Organometallic Chemistry, 664, 288-293.

Permanent Research Commons link: https://hdl.handle.net/10289/212

Abstract

Reaction of cyclomanganated aryl ketones with CS₂ proceeds with insertion into the Mn–C bond to give η²-dithiocarboxylato–Mn(CO)₄ compounds. With other cyclomanganated substrates such as that from Ph₃P=S and also with Mn₂(CO)₁₀, CS₂ gives (μ₃-CS₃)₂Mn₄(CO)₁₆ with bridging trithiocarbonate ligands.

Date

2002-01-01

Type

Journal Article

Publisher

Elsevier SA

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Science and Engineering Papers [3122]