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      A structural isomer of the [CoFe3(CO)13]− anion

      Evans, Cameron; Nicholson, Brian K.
      DOI
       10.1016/S0022-328X(01)01356-0
      Link
       www.sciencedirect.com.ezproxy.waikato.ac.nz:2048
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      Citation
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      Evans, C. & Nicholson, B.K. (2002). A structural isomer of the [CoFe3(CO)13]- anion. Journal of Organometallic Chemistry, 645(1-2), 281-285.
      Permanent Research Commons link: https://hdl.handle.net/10289/223
      Abstract
      The crystal structure of [Et4N][CoFe3 (CO) 13] has been determined, and shown to contain an anion with the CO ligands adopting a very different arrangement about the tetrahedral CoFe3 core to that found for the same anion, reported previously for the PPN+ salt. The relationship between the two structures can be understood in terms of Johnson's Ligand Polyhedral Model. In contrast the anion in [Et4N][CoRu3 (CO) 13] has the same geometry as that described in the corresponding PPN+ salt.
      Date
      2002-02-01
      Type
      Journal Article
      Publisher
      Elsevier
      Rights
      This article is published in the Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V.
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      • Science and Engineering Papers [3116]
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