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dc.contributor.authorHenderson, William
dc.contributor.authorKilpin, Tracey D.
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2009-07-16T04:18:12Z
dc.date.available2009-07-16T04:18:12Z
dc.date.issued2007
dc.identifier.citationHenderson, W., Kilpin, T. D. & Nicholson, B. K. (2007). (p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor ligand. Structural Chemistry, 19(2), 199-202.en
dc.identifier.issn1572-9001
dc.identifier.urihttps://hdl.handle.net/10289/2681
dc.description.abstractThe title compound was prepared from the (p-cymene)ruthenium chloride dimer and thioglycollic acid. The structure is a centrosymmetric dimer bridged by the soft-base S atoms, with the hard-base O atoms of the carboxylate group chelating to form a five-membered twisted-ring. The coordination of the ruthenium atoms is completed by a η6-p-cymene ligand, giving an 18-electron count. The Ru–S bonds are essentially equal at 2.396(1) Å.en
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherSpringeren_NZ
dc.relation.urihttp://www.springerlink.com/content/c133m96j28447420/?p=0d316f144b4e47b5ad9752ab00878f34&pi=42en
dc.rightsThis is the author's accepted version of an article published in the journal: Structural Chemistry. The original publication is available at www.springerlink.com.en
dc.subjectrutheniumen
dc.subjectthioglycollateen
dc.subjectcrystal structureen
dc.subjects-bridged dimeren
dc.title(p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor liganden
dc.typeJournal Articleen
dc.identifier.doi10.1007/s11224-007-9272-9en
dc.relation.isPartOfStructural Chemistryen_NZ
pubs.begin-page199en_NZ
pubs.elements-id33293
pubs.end-page202en_NZ
pubs.issue2en_NZ
pubs.volume19en_NZ


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