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dc.contributor.authorBruce, Michael I.
dc.contributor.authorBurgun, Alexandre
dc.contributor.authorKramarczuk, Kathy A.
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorParker, Christian R.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorWhite, Allan H.
dc.contributor.authorZaitseva, Natasha N.
dc.date.accessioned2009-08-03T22:12:29Z
dc.date.available2009-08-03T22:12:29Z
dc.date.issued2008
dc.identifier.citationBruce, M. I., Burgun, A., Kramarczuk, K. A., Nicholson, B. K., Parker, C. R., Skelton, B. W., White, A. H. & Zaitseva, N. N. (2008). Tricyanovinylalkynyl–metal complexes: synthesis and some reactions. Dalton Transactions, 7(1), 33-36.en
dc.identifier.urihttps://hdl.handle.net/10289/2732
dc.description.abstractReactions of Group 8 metal ethynyls with tetracyanoethene afford tricyanovinylethynyl–metal derivatives, M{C≡CC(CN)=C(CN)2}(PP)Cp’ [2; M = Ru, Os; PP = (PPh3)2, dppe;Cp’=Cp,Cp*; not all combinations]; a similar reaction occurs with the vinylidene RuCl(=C=CHPh)(PPh3)Cp. Further replacement of a CNgroup in 2 occurs with nucleophiles, while homo- and hetero-metallic derivatives are obtained by coordination of one of the remaining CN groups to other metal–ligand fragments.en
dc.language.isoen
dc.publisherRoyal Society of Chemistryen_NZ
dc.relation.urihttp://www.rsc.org/ej/DT/2009/b810720c.pdfen
dc.subjectchemistryen
dc.subjectTricyanovinylalkynyl–metalen
dc.titleTricyanovinylalkynyl–metal complexes: synthesis and some reactionsen
dc.typeJournal Articleen
dc.identifier.doi10.1039/b810720cen
dc.relation.isPartOfDalton Transactionsen_NZ
pubs.begin-page33en_NZ
pubs.elements-id33751
pubs.end-page36en_NZ
pubs.issue1en_NZ
pubs.volume7en_NZ


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