dc.contributor.author | Bruce, Michael I. | |
dc.contributor.author | Burgun, Alexandre | |
dc.contributor.author | Kramarczuk, Kathy A. | |
dc.contributor.author | Nicholson, Brian K. | |
dc.contributor.author | Parker, Christian R. | |
dc.contributor.author | Skelton, Brian W. | |
dc.contributor.author | White, Allan H. | |
dc.contributor.author | Zaitseva, Natasha N. | |
dc.date.accessioned | 2009-08-03T22:12:29Z | |
dc.date.available | 2009-08-03T22:12:29Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Bruce, M. I., Burgun, A., Kramarczuk, K. A., Nicholson, B. K., Parker, C. R., Skelton, B. W., White, A. H. & Zaitseva, N. N. (2008). Tricyanovinylalkynyl–metal complexes: synthesis and some reactions. Dalton Transactions, 7(1), 33-36. | en |
dc.identifier.uri | https://hdl.handle.net/10289/2732 | |
dc.description.abstract | Reactions of Group 8 metal ethynyls with tetracyanoethene afford tricyanovinylethynyl–metal derivatives, M{C≡CC(CN)=C(CN)2}(PP)Cp’ [2; M = Ru, Os; PP = (PPh3)2, dppe;Cp’=Cp,Cp*; not all combinations]; a similar reaction occurs with the vinylidene RuCl(=C=CHPh)(PPh3)Cp. Further replacement of a CNgroup in 2 occurs with nucleophiles, while homo- and hetero-metallic derivatives are obtained by coordination of one of the remaining CN groups to other metal–ligand fragments. | en |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | en_NZ |
dc.relation.uri | http://www.rsc.org/ej/DT/2009/b810720c.pdf | en |
dc.subject | chemistry | en |
dc.subject | Tricyanovinylalkynyl–metal | en |
dc.title | Tricyanovinylalkynyl–metal complexes: synthesis and some reactions | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1039/b810720c | en |
dc.relation.isPartOf | Dalton Transactions | en_NZ |
pubs.begin-page | 33 | en_NZ |
pubs.elements-id | 33751 | |
pubs.end-page | 36 | en_NZ |
pubs.issue | 1 | en_NZ |
pubs.volume | 7 | en_NZ |