Identification of the water amidogen radical complex
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Abstract
The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.
Citation
Ennis, C. P., Lane, J. R., Kjaergarrd, H. G. & McKinley, A. J. (2009). Identification of the water amidogen radical complex. Journal of the American Chemical Society, 131(4), 1358-1358.
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American Chemical Society