Research Commons
      • Browse 
        • Communities & Collections
        • Titles
        • Authors
        • By Issue Date
        • Subjects
        • Types
        • Series
      • Help 
        • About
        • Collection Policy
        • OA Mandate Guidelines
        • Guidelines FAQ
        • Contact Us
      • My Account 
        • Sign In
        • Register
      View Item 
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      JavaScript is disabled for your browser. Some features of this site may not work without it.

      Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene)

      Yeo, Jeremy S.L.; Vittal, Jagadese J.; Henderson, William; Hor, T.S. Andy
      Link
       pubs.acs.org
      Citation
      Export citation
      Yeo, J. S. L., Vittal, J. J., Henderson, W., Hor, T. S. A. (2000). Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene). Inorganic Chemistry, 41, 1194-1198.
      Permanent Research Commons link: https://hdl.handle.net/10289/2877
      Abstract
      Pt₂(μ-Se)₂(PPh₃)₄ reacts with PtCl₂(cod) to give {Pt₂(μ₃-Se)₂(PPh₃)₄[Pt(cod)]}²⁺ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}²⁺. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.
      Date
      2002
      Type
      Journal Article
      Rights
      This article is published in the Journal of Inorganic Chemistry. (c) 2002 American Chemical Society
      Collections
      • Science and Engineering Papers [3069]
      Show full item record  

      Usage

       
       

      Usage Statistics

      For this itemFor all of Research Commons

      The University of Waikato - Te Whare Wānanga o WaikatoFeedback and RequestsCopyright and Legal Statement