| dc.contributor.author | Yeo, Jeremy S.L. | |
| dc.contributor.author | Vittal, Jagadese J. | |
| dc.contributor.author | Henderson, William | |
| dc.contributor.author | Hor, T.S. Andy | |
| dc.date.accessioned | 2009-08-26T20:49:31Z | |
| dc.date.available | 2009-08-26T20:49:31Z | |
| dc.date.issued | 2002 | |
| dc.identifier.citation | Yeo, J. S. L., Vittal, J. J., Henderson, W., Hor, T. S. A. (2000). Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene). Inorganic Chemistry, 41, 1194-1198. | en |
| dc.identifier.uri | https://hdl.handle.net/10289/2877 | |
| dc.description.abstract | Pt₂(μ-Se)₂(PPh₃)₄ reacts with PtCl₂(cod) to give {Pt₂(μ₃-Se)₂(PPh₃)₄[Pt(cod)]}²⁺ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}²⁺. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected. | en |
| dc.language.iso | en | |
| dc.relation.uri | http://pubs.acs.org/doi/abs/10.1021/ic010905t | en |
| dc.rights | This article is published in the Journal of Inorganic Chemistry. (c) 2002 American Chemical Society | en |
| dc.subject | chemistry | en |
| dc.subject | electrospray mass spectrometry | en |
| dc.subject | metal scrambling | en |
| dc.subject | isolation | en |
| dc.subject | directed synthetic methodology | en |
| dc.title | Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene) | en |
| dc.type | Journal Article | en |
