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dc.contributor.authorDyson, Paul J.
dc.contributor.authorEllis, David J.
dc.contributor.authorHenderson, William
dc.contributor.authorLaurenczy, Gabor
dc.date.accessioned2009-11-10T20:41:49Z
dc.date.available2009-11-10T20:41:49Z
dc.date.issued2003
dc.identifier.citationDyson, P. J., Ellis, D. J., Henderson, W., & Laurenczy, G. (2003). A comparison of ruthenium-catalysed arene hydrogenation reactions in water and 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids. Advanced Synthesis & Catalysis, 345(1/2), 216-221.en
dc.identifier.urihttps://hdl.handle.net/10289/3358
dc.description.abstractThe hydrogenation of benzene and other arene substrates under biphasic conditions is evaluated using the catalyst precursor Ru(n₆-C₁₀H₁₄)(pta)Cl₂(pta=1,3,5-triaza-7-phosphaadamantane) immobilised in water and 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids. The effect that contamination of the 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids with chloride has on the hydrogenation reaction has also been examined. Of the immobilisation solvents tested the optimum solvent was found to be chloride-free 1- butyl-3-methylimidazolium tetrafluoroborate. Catalytic turnovers in this solvent are highest, and in general, turnovers for the hydrogenation reactions follow the trend: chloride-free 1-butyl-3-methylimidazolium tetrafluoroborate > water > chloridecontaminated 1-butyl-3-methylimidazolium tetrafluoroborate.en
dc.language.isoen
dc.publisherWiley - VCHen_NZ
dc.subjectarenesen
dc.subjectbiphasic catalysisen
dc.subjecthydrogenationen
dc.subjectionic liquidsen
dc.subjectrutheniumen
dc.subjectwater as solventen
dc.titleA comparison of ruthenium-catalysed arene hydrogenation reactions in water and 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquidsen
dc.typeJournal Articleen
dc.identifier.doi10.1002/adsc.200390015en
dc.relation.isPartOfAdvanced Synthesis and Catalysisen_NZ
pubs.begin-page216en_NZ
pubs.elements-id28218
pubs.end-page221en_NZ
pubs.issue1-2en_NZ
pubs.volume345en_NZ


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