Bis[μ-bis(diphenylphosphino)methane-К²P:P’]bis[(saccharinato-КN)-
palladium(I)] dichloromethane solvate

Henderson, William; Nicholson, Brian K.; Chung, Dong C.

doi:10.1107/S1600536802012515

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DOI

10.1107/S1600536802012515

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Henderson, W., Nicholson, B. K., & Chung, D. C. (2002). Bis[μ-bis(diphenylphosphino)methane-К²P:P’]bis[(saccharinato-КN)- palladium(I)] dichloromethane solvate. Acta Crystallographica Section E, 58(8), 432-433.

Permanent Research Commons link: https://hdl.handle.net/10289/3379

Abstract

The dimeric palladium(I) saccharinate complex [Pd₂(sac)₂(dppm)₂], has been characterized as its di¬chloro¬methane solvate, i.e. [Pd₂(C₇H₄NO₃S)₂(C₂₅H₂₂P₂)₂]•CH₂Cl₂. The complex features a Pd—Pd bond bridged by two dppm ligands, with the saccharinate ligands N-bonded trans to the Pd—Pd bond.

Date

2002

Type

Journal Article

Publisher

BLACKWELL MUNKSGAARD

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This is an authorised electronic reprint of an artilce published in the journal: Acta Crystallographica, Section E.

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