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dc.contributor.authorAlley, Steven R.
dc.contributor.authorHenderson, William
dc.date.accessioned2009-11-20T02:00:19Z
dc.date.available2009-11-20T02:00:19Z
dc.date.issued2001
dc.identifier.citationAlley, S. R., & Henderson, W. (2001). New ferrocene-derived hydroxymethylphosphines: FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and the dppf analogue 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵-C₅H₄)₂]. Inorganic Chemistry Communications, 4(12), 741-744.en
dc.identifier.urihttps://hdl.handle.net/10289/3404
dc.description.abstractReactions of the ferrocene-phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess formaldehyde gives the new hydroxymethylphosphines FcP(CH₂OH)₂ 1 and 1,1′-Fc′[P(CH₂OH)₂]₂ 2, respectively. Phosphine 1 is an air-stable crystalline solid, whereas 2 is isolated as an oil. Reaction of 1 with H₂O₂, S₈ or Se gives the chalcogenide derivatives FcP(E)(CH₂OH)₂ (E=O, S or Se), whilst reaction of 2 with S8 gives 1,1′-Fc′[P(S)(CH₂OH)₂]₂, which were fully characterised. Phosphine 1 was also characterised by an X-ray crystal structure determination.en
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherELSEVIER SCIENCE BVen_NZ
dc.rightsThis is an author’s accepted version of an article published in the journal: Inorganic Chemistry Communications. Copyright © 2001 Elsevier Science B.V. All rights reserved.en
dc.subjectferrocene compoundsen
dc.subjecthydroxymethylphosphinesen
dc.subjectcrystal structureen
dc.subjectphosphine chalcogenidesen
dc.titleNew ferrocene-derived hydroxymethylphosphines: FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and the dppf analogue 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵-C₅H₄)₂]en
dc.typeJournal Articleen
dc.identifier.doi10.1016/S1387-7003(01)00309-4en
dc.relation.isPartOfInorganic Chemistry Communicationsen_NZ
pubs.begin-page741en_NZ
pubs.elements-id27192
pubs.end-page744en_NZ
pubs.issue12en_NZ
pubs.volume4en_NZ


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