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      Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)

      Neo, Kian Eang; Huynh, Han Vinh; Koh, Lip Lin; Henderson, William; Hor, T.S. Andy
      DOI
       10.1016/j.jorganchem.2007.11.031
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      Neo, K. E., Huynh, H. V., Koh, L. L., Henderson, W., Hor, T. S. A. (2008). Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II). Journal of Organometallic Chemistry, 693(8/9), 1628-1635.
      Permanent Research Commons link: https://hdl.handle.net/10289/3429
      Abstract
      Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = −CH(CH₂CH₂PPh₂)₂) reacts with AgNO₃ to give [Pd(NO₃)(PCP)] (2). Similar reaction with AgBF₄ gives the aqua complex [Pd(OH₂)(PCP)][BF₄] (3) and the dinuclear complex [{Pd(PCP)}₂(μ-Cl)][BF₄] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki–Miyaura coupling between aryl bromides and phenyl boronic acid.
      Date
      2008
      Type
      Journal Article
      Publisher
      Elsevier
      Collections
      • Science and Engineering Papers [3143]
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