Abstract
Routes to the synthesis of the mixed sulfide-phenylthiolate complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ have been explored; reaction of [Pt₂(μ-S)₂(PPh₃)₄] with excess Ph₂IBr proceeds readily to selectively produce this complex, which was structurally characterised as its PF₆⁻ salt. Reactions of [Pt₂(μ-S)₂(PPh₃)₄] with other potent arylating reagents (1-chloro-2,4-dinitrobenzene and 1,5-difluoro-2,4-dinitrobenzene) also produce the corresponding nitroarylthiolate complexes [Pt₂(μ-S){μ -SC₆H₂(NO₂)₂X}(PPh₃)₄]⁺ (X = H, F). The complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ reacts with Me₂SO₄ to produce the mixed alkyl/aryl bis-thiolate complex [Pt₂(μ-SMe)(μ -SPh)(PPh₃)₄]²⁺, but corresponding reactions with the nitroarylthiolate complexes are plagued by elimination of the nitroaryl group and formation of [Pt₂(μ-SMe)₂(PPh₃)₄]²⁺. [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ also reacts with Ph₃PAuCl to give [Pt₂(μ-SAuPPh₃)(μ -SPh)(PPh₃)₄]²⁺.
Type
Journal Article
Type of thesis
Series
Citation
Deadman, B. J., Henderson, W., Nicholson, B. K., Petchell, L. E., Rose, S. L., & Hor, T. S. A. (2009). The arylation of [Pt₂(μ-S)₂(PPh₃)₄]. Inorganica Chimica Acta.
Date
2009
Publisher
Elsevier
Degree
Supervisors
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Publisher version