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      Platinum(II), palladium(II), nickel(II), and gold(I) complexes of the “electrospray-friendly” thiolate ligands 4-SC₅H₄N- and 4-SC₆H₄OMe-

      Decker, Corry; Henderson, William; Nicholson, Brian K.
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      Henderson 2010 Platinum(II).pdf
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      DOI
       10.1080/00958972.2010.507270
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      Decker, C., Henderson, W. & Nicholson, B. K. (2010). Platinum(II), palladium(II), nickel(II), and gold(I) complexes of the “electrospray-friendly” thiolate ligands 4-SC₅H₄N- and 4-SC₆H₄OMe-. Journal of Coordination Chemistry, 63(17), 2965-2975.
      Permanent Research Commons link: https://hdl.handle.net/10289/4377
      Abstract
      The series of platinum(II), palladium(II), and nickel(II) complexes [ML₂(dppe)] [M = Ni, Pd, Pt; L = 4-SC₅H₄N or 4-SC₆H₄OMe; dppe = Ph₂PCH₂CH₂PPh₂] containing pyridine-4-thiolate or 4-methoxybenzenethiolate ligands, together with the corresponding gold(I) complexes [AuL(PPh3)], were prepared and their electrospray ionization mass spectrometric behavior compared with that of the thiophenolate complexes [M(SPh)₂(dppe)] (M = Ni, Pd, Pt) and [Au(SPh)(PPh₃)]. While the pyridine-4-thiolate complexes yielded protonated ions of the type [M + H]+ and [M + 2H]²+ ions in the Ni, Pd, and Pt complexes, an [M + H]+ ion was only observed for the platinum derivative of 4-methoxybenzenethiolate. Other ions, which dominated the spectra of the thiophenolate complexes, were formed by thiolate loss and aggregate formation. The X-ray crystal structure of [Pt(SC₆H₄OMe-4)₂(dppe)] is also reported.
      Date
      2010-09
      Type
      Journal Article
      Publisher
      Taylor & Francis
      Rights
      This is an electronic version of an article published in the Journal of Coordination Chemistry, which is available online at: www.tandfonline.com
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      • Science and Engineering Papers [3019]
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