Self-assembly of a columnar polymeric calcium phosphinate derived from camphene

Henderson, William; Leach, Meto T.; Nicholson, Brian K.; Sabat, Michal

doi:10.1039/DT9950002109

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Henderson, W., Leach, M.T., Nicholson, B.K. & Sabat, M. (1995). Self-assembly of a columnar polymeric calcium phosphinate derived from camphene. Journal of the Chemical Society, Dalton Transactions, 12, 2109-2110.

Permanent Research Commons link: https://hdl.handle.net/10289/4697

Abstract

(2,2-Dimethylbicyclo[2.2.1] hept-3-ylmethyl)phosphinic acid (RPO₂H₂), readily prepared from camphene and hypophosphorous acid, formed a polymeric calcium salt [{Ca(RPO₂H) ₂ (RPO₂H₂)(H₂O)}n], with both terminal and triply bridging phosphinate groups, and an overall columnar structure with an inorganic core and a pseudo-close-packed sheath of terpene moieties.

Date

1995

Type

Journal Article

Publisher

The Royal Society of Chemistry

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Science and Engineering Papers [2525]